Everything about Carbon-nitrogen Bond totally explained
A
carbon-nitrogen bond is a
covalent bond between
carbon and
nitrogen and one of the most abundant in
organic chemistry and
biochemistry .
Nitrogen has five
valence electrons and in simple amines it's
trivalent with two remaining electrons forming a
lone pair. Through it, nitrogen can form an additional bond to
hydrogen making it
tetravalent and with a positive charge in
ammonium salts. Many nitrogen compounds can thus be potentially
basic but its degree depends on the configuration: the nitrogen atom in
amides isn't basic due to delocalization of the lone pair into a double bond and in
pyrrole the lone pair is part of an aromatic sextet.
In common with
carbon-carbon bonds, these bonds can be stable
double bonds for instance
imines and
triple bonds such as
nitriles.
Bond lengths range from 147.9
pm for simple
amines to 147.5 pm for C-N= compounds such as
nitromethane to 135.2 pm for partial double bonds in
pyridine to 115.8 pm for triple bonds as in
nitriles . The
bond strength in a CN bond is higher (184
kcal/
mol) than that of the CC bond (145 kcal/mol)
[ ]
A CN bond is strongly polarized towards nitrogen (Electronegativity C vs N = 2.55:3.04) and subsequently molecular dipole moments can be high: cyanamide 4.27D, diazomethane 1.5 D, methyl azide 2.17, pyridine 2.19. For this reason many compounds containing CN bonds are water-soluble.
Nitrogen functional groups
Further Information
Get more info on 'Carbon-nitrogen Bond'.
|
External Link Exchanges
Do you know how hard it is to get a link from a large encyclopaedia? Well we're different and will prove it. To get a link from us just add the following HTML to your site on a relevant page:
<a href="http://carbon-nitrogen_bond.totallyexplained.com">Carbon-nitrogen bond Totally Explained</a>
Then simply click through this link from your web page. Our crawlers will verify your link, extract the title of your web page and instantly add a link back to it. If you like you can remove the words Totally Explained and embed the link in article text.
As long as your link remains in place, we'll keep our link to you right here. Please play fair - our crawlers are watching. Your site must be closely related to this one's topic. Any kind of spamming, dubious practises or removing the link will result in your link from us being dropped and, potentially, your whole site being banned. |
